Crystal structure of μ-oxalato-κ2 O 1:O 2-bis[(dimethyl sulfoxide-κO)triphenyltin(IV)]
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چکیده
In the previously reported [C2O4(SnPh3)2] complex [Diop et al. (2003 ▸). Appl. Organomet. Chem.17, 881-882.], the SnIV atoms are able to formally complete their coordination by addition of dimethyl sulfoxide (DMSO) mol-ecules provided by the reaction medium, affording the title complex, [Sn2(C6H5)6(C2O4)(C2H6OS)2]. The SnIV atoms are then penta-coordinated, with a common trans trigonal-bipyramidal arrangement. The asymmetric unit contains one half-mol-ecule, which is completed by inversion symmetry in space group type C2/c. The inversion centre is placed at the mid-point of the central bis-monodentate oxalate dianion, C2O42-, which bridges the [(SnPh3)(DMSO)] moieties. The mol-ecule crystallizes as a disordered system, with two phenyl rings disordered by rotation about their Sn-C bonds, while the DMSO mol-ecule is split over two positions due to a tetra-hedral inversion at the S atom. All disordered parts were refined with occupancies fixed of 0.5.
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Bis(dimethyl sulfoxide-κO)bis(mercaptoacetato-κ2 O,S)tin(IV)
In the title compound, [Sn(C(2)H(2)O(2)S)(2)(C(2)H(6)OS)(2)], the mercaptoacetato ligands chelate to Sn(IV) through S and one O atoms. The metal centre is also coordinated by two dimethyl sulfoxide (DMSO) ligands through the O atom, leading to an overall distorted octahedral coordination environment for the Sn(IV) atom. The mol-ecular adduct lies on a twofold rotation axis.
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